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Estudio de titulación potenciométrica del control de la incrustación de CaCO3 con películas de polieterimida y polieterimida sulfonada no solubles en agua

dc.contributor.authorCorrea Muñoz, Estefania
dc.contributor.authorButto Miranda, Nicole
dc.contributor.authorParra Muñoz, Nicole
dc.contributor.authorBlanco Leal, Adriana
dc.contributor.authorSanta Arango, Alejandra María
dc.contributor.authorDíaz Soler, Felipe
dc.contributor.authorYazdani-Pedram, Mehrdad
dc.contributor.authorCabrera Barjas, Gustavo
dc.contributor.authorOstos Ortiz, Carlos Eduardo
dc.contributor.authorGracia, Francisco
dc.contributor.authorNeira Carrillo, Andrónico David
dc.coverage.spatialColombiaen_US
dc.date.accessioned2025-11-18T16:23:27Z
dc.date.available2025-11-18T16:23:27Z
dc.date.issued2024-10-01
dc.identifier.issn0011-9164en_US
dc.identifier.urihttps://repositorioinstitucional.ufpso.edu.co/xmlui/handle/20.500.14167/6073
dc.description.abstractLa titulación potenciométrica automática (TPA) es un método de análisis químico para estudiar la cristalización de CaCO₃ en solución. Demostramos la utilidad de la TPA para estudiar la cristalización de CaCO₃ utilizando películas de polímero insolubles en agua, ideales para el estudio de superficies expuestas a iones Ca²⁺ y CO₃²⁻ con capacidad para eliminar Ca²⁺ y/o susceptibles a la formación de incrustaciones, como superficies de equipos, superficies de intercambio iónico o membranas de desalinización. Se prepararon películas de polieterimida (PEI) y polieterimida sulfonada (SPEI) mediante la técnica de moldeo por disolución, y su superficie se estudió mediante FESEM, XPS, potencial Z y ángulo de contacto. Se realizaron ensayos de TPA con las películas de polímero, utilizando un tampón de carbonato (pH 9) con CaCl₂ añadido, y monitorizando el Ca²⁺ libre. Las curvas de TPA con PEI no mostraron diferencias significativas respecto al control, mientras que la presencia de la película de SPEI afectó la cinética de formación de CaCO₃. Esto se evidenció por los cambios en la pendiente y el máximo de las curvas de TPA. Los análisis FTIR, XRD y FESEM de las películas poliméricas y del CaCO₃ tras los ensayos APT demostraron el control sobre los tipos de polimorfos de CaCO₃. Demostramos que la película SPEI es una buena candidata para retrasar la formación de CaCO₃ en agua, mediante la adsorción de iones Ca²⁺ y la adsorción de agregados de pre-nucleación de CaCO₃.en_US
dc.language.isoen_USen_US
dc.relationhttps://www.sciencedirect.com/science/article/abs/pii/S0011916424005939en_US
dc.titleEstudio de titulación potenciométrica del control de la incrustación de CaCO3 con películas de polieterimida y polieterimida sulfonada no solubles en aguaen_US
dc.title.translatedPotentiometric titration study of CaCO3 scaling control with non-water soluble polyetherimide and sulfonated polyetherimide filmsen_US
dc.contributor.cvlacEstefania Correa Muñoz [0001587524]en_US
dc.contributor.cvlacAlejandra Maria Santa Arango [0000146765]en_US
dc.contributor.cvlacCarlos Eduardo Ostos Ortiz [0000214809]en_US
dc.contributor.googlescholarNicole Butto Miranda [z7mGOcEAAAAJ]en_US
dc.contributor.googlescholarAdriana Blanco Leal [UG0w-4QAAAAJ]en_US
dc.contributor.googlescholarMehrdad Yazdani-Pedram [njP0LAwAAAAJ]en_US
dc.contributor.googlescholarGustavo Cabrera Barjas [r4wZOggAAAAJ]en_US
dc.contributor.googlescholarCarlos Eduardo Ostos Ortiz [2qxliQ8AAAAJ]en_US
dc.contributor.orcidNicole Parra Muñoz [0000-0002-8604-5343]en_US
dc.contributor.orcidAdriana Blanco Leal [0000-0002-2864-4778]en_US
dc.contributor.orcidAlejandra Maria Santa Arango [0000-0002-0446-3657]en_US
dc.contributor.orcidMehrdad Yazdani Pedram [0000-0002-8211-3652]en_US
dc.contributor.orcidGustavo Cabrera Barjas [0000-0002-1850-0244]en_US
dc.contributor.orcidCarlos Eduardo Ostos Ortiz [0000-0003-0983-1823]en_US
dc.contributor.orcidFrancisco Gracia [0000-0001-5266-3234]en_US
dc.contributor.orcidAndrónico David Neira Carrillo [0000-0003-0060-7518]en_US
dc.contributor.scopusEstefania Correa Muñoz [59094958600]en_US
dc.contributor.scopusNicole Butto Miranda [57964206500]en_US
dc.contributor.scopusNicole Parra Muñoz [57212455863]en_US
dc.contributor.scopusAdriana Blanco Leal [59096494600]en_US
dc.contributor.scopusAlejandra Maria Santa Arango [59097538200]en_US
dc.contributor.scopusFelipe Díaz Soler [57200503736]en_US
dc.contributor.scopusMehrdad Yazdani Pedram [7003761834]en_US
dc.contributor.scopusGustavo Cabrera Barjas [57217424937]en_US
dc.contributor.scopusCarlos Eduardo Ostos Ortiz [24559580800]en_US
dc.contributor.scopusFrancisco Gracia [12139463800]en_US
dc.contributor.scopusAndrónico David Neira Carrillo [24468723400]en_US
dc.description.abstractenglishAutomatic potentiometric titration (APT) is a chemical analysis method to study the crystallization of CaCO3 in solution. We demonstrate how APT is also valuable for studying CaCO3 crystallization using water-insoluble polymer films, ideal for studying surfaces exposed to Ca2+ and CO32− ions with the capacity to remove Ca2+ and/or susceptible to scale formation, equipment surfaces, ion exchange surfaces or desalination membranes, etc. Polyetherimide (PEI) and sulfonated polyetherimide (SPEI) films were prepared by solvent casting technique, and their surface studied using FESEM, XPS, Z potential, and contact angle. APT assays were performed with polymer films, using a carbonate buffer (pH 9), dosed with CaCl2, and monitoring free Ca2+. The APT curves with PEI showed no significant difference compared to the control, while the presence of SPEI film affected the kinetics of CaCO3 formation. This was evidenced by changes in the slope and peak maximum of the APT curves. FTIR, XRD, and FESEM of the polymeric films and the CaCO3 after the APT assays showed control over the types of CaCO3 polymorphs. We show that the SPEI film is a good candidate to delay the formation of CaCO3 in water, through the adsorption of Ca2+ ions and the adsorption of pre-nucleation clusters of CaCO3.en_US
dc.subject.proposalValoración potenciométrica automática (APT)en_US
dc.subject.proposalCaCO₃en_US
dc.subject.proposalIncrustaciónen_US
dc.subject.proposalPelículas de polímeroen_US
dc.subject.proposalCaracterización de superficiesen_US
dc.subject.proposalPolieterimida sulfonada (SPEI)en_US
dc.subject.keywordsAutomatic potentiometric titration (APT)en_US
dc.subject.keywordsCaCO3en_US
dc.subject.keywordsscalingen_US
dc.subject.keywordsPolymer filmsen_US
dc.subject.keywordsSurface characterizationen_US
dc.subject.keywordsSulfonated polyetherimide (SPEI)en_US
dc.publisher.facultyFacultad ingenieríasen_US
dc.type.redcolhttp://purl.org/redcol/resource_type/ARTen_US
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dc.identifier.DOIhttps://doi.org/10.1016/j.desal.2024.117882en_US


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